Given the fact that BlackBerry Professional Software is brand new and I bet a few people are jumping on the bandwagon to go from SBE to BPS, I figured I'd post this KB from RIM ... haven't tried this myself though so I don't know of the problem mentioned.
KB14842 - Migrating BlackBerry Enterprise Server for Microsoft Exchange 4.1.4 Small Business Edition to BlackBerry Professional Software 4.1.4 results in failure to install Dispatcher and Router services
The solution is to Uninstall and then reinstall BlackBerry Professional Software 4.1.4.