It seems that I have got to the bottom of the problem as such.
Prior to me synching my BB, my DM had told me if I wanted to update the BB with various updates. I said yes, but after a few mins it said it had completed it, which didn't ring true especially when the upgrade to 4.5 took well over an hour. So I can only assume it hadn't fully run the updates. The problem with synching actually happened not long after that. It never crossed my mind about the updates being the problem.
Anyway, tonight DM told me it had quite a few updates to make, which I allowed and it took less time than the upgrade to 4.5. I rebooted the BB a couple of times to make sure, and all is well in the synching department - it added the 37 items from my BB back onto my Outlook!
I would like to thank the people above in their suggestions and help. I hope this solution will help someone else if they have the same problem.
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