RIM servers check your email servers every 15 minutes and pushes mail that is found to the BB. If mail was found, RIM will repoll in 2-3 minutes and again push what is found and continue on that cycle until nothing is there. At that time, RIM reverts to the 15 minute cycle and things start from there.
As for mail on the server, if you do not have "Leave mail on server" checked on your PC email client, once that mail is downloaded to the PC, it is deleted from the server and hence cannot be pulled by RIM and pushed to the BB.
Email is pulled and pushed only once to the device - same as wil your PC client. Mail already sent to the BB, but left on the server is available for download to your PC email client and vice versa - again, as long as "Leave mail on server" is checked.
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